Number of hours
- Lectures 10.5
- Projects -
- Tutorials 12.0
- Internship -
- Laboratory works 6.0
- Written tests 1.5
ECTS
ECTS 0.0
Sandrine BRICE-PROFETA
Content(s)
Kinetic
*Rate Theories*
- Introduction to elementary processes
- Collision theory
- Presentation of the theory of the activated complex
*Reaction Mechanisms*
- Formal kinetics
- Simple order reactions
- Compound reactions: Reversible reactions - Consecutive reactions, quasi-steady state approximation
- Mechanism of complex reactions
- Kinetic Principles
- Stage reactions
- Free radical chain reactions, chain length
- Catalysis: definition, homogeneous, heterogeneous, enzymatic catalysis
- Catalysis and catalytic cycles
**Kinetic Chemistry practical work (2x3H): (examples)**
- kinetic monitoring by UV-Vis spectroscopy
- monitoring by assay and conductimetry of ester hydrolysis
Thermodynamics
*Second principle*
*Second principle applied to chemical thermodynamics
*Notion of entropy, standard entropy, influence of T and p
*Free enthalpy G
*Chemical potential*
*Chemical Potential: definition, properties, influence of T and p, standard chemical potential
*Condition of physico-chemical balance
*Equilibrium between phases: Clapeyron diagrams in unary systems
*Expression of chemical potential: ideal and real systems
*Activity and activity coefficient Equilibrium constant
**Chemical equilibrium Variance of an equilibrium **
*Displacement of balances: Le Chatelier's law
The course exists in the following branches:
- Curriculum - Prépa - Semester 3
- Curriculum - Prépa SHN - Semester 3
Course ID : 2CLCHS3
Course language(s):
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